求大神帮忙翻一下

An 8-fold interpenetrating diamondoid network, [Ni(cyclam)] 2
[TCM] â
2DMF â10H 2
O, has been prepared by the self-assembly of a Ni-
(II)cyclam macrocyclic complex and sodium tetrakis[4-(carboxyphenyl)-
oxamethyl]methane in DMF/water. The network shows an unusual
[4 + 4] mode of interpenetration, generating 1D channels of
effective window size 6.7 Å × 4.7 Å. The network shows flexible
behavior: it becomes nonporous on removal of the guest molecules
occupying the channels, but the open structure is restored when
the desolvated solid is immersed in the mixture of H
2
O/DMF (1:1,
v/v) for 5 min. The desolvated host has different binding capacities
for n-butanol, pyridine, and ethanol.

Assembly of metal-organic open frameworks (MOFs) has
attracted great attention, and MOFs with various network
topologies have been prepared from the metal and organic
building blocks.They have the potential for being applied
to selective molecular recognition and separation,gasstorage,ion-exchange,
and heterogeneous catalysis.It is
of interest to build diamondoid networks with big cavities
because they have the perspective to be used as porous
materials or for a catalytic purpose. Interpenetrating dia-mondoid networks with open structures including counterions
and guest molecules have been demonstrated.
Our design strategy was to build a neutral diamondoid
network by interconnecting a big pseudotetrahedral anionic
ligand and a metal ion having two coordination sites at the
trans position (Scheme 1). We chose tetrakis[4-(carboxyphe-nyl)oxamethyl]methane (TCM) ligand

金属有机骨架（MOFs）自组装的极大关注，并与各种networktopologies MOFs材料已经从金属制备有机建造块。他们被用于选择性分子识别、分离，库，离子交换的潜力，和多相催化。它有兴趣建立与大cavitiesbecause他们作为porousmaterials或催化目的看钻石网络。互穿网络直径mondoid包括counterionsand客体分子的开放结构已被证明。我们的设计策略是由相互连接的一大anionicligand四面体和跨位具有两个配位点的金属离子的建立一个中立的diamondoidnetwork（方案1）。我们选择了四[ 4（carboxyphe NYL）oxamethyl ]甲烷（中医）配体

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